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Question

40 g of glucose (Molar mass =180) is mixed with 200 mL of water. The freezing point of solution is ________K. (Nearest integer)
[Given:Kf=1.86 K mol1 Density of water=1.00 g cm3; Freezing point water =273.15 K]

A
271.0
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B
271
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C
271.00
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Solution

Freezing point depression of a solution is given by,
Tf=i×Kf×m
where,
Tf is the depression in freezing point.
Kf is molal depression constant.
m is molality of solution.
Van't hoff factor, i=1 for glucose)
Molality (m)=wsoluteM×1000Wsolvent
where,
w is weight of solute
W is weight of solvent
M is molar mass of the solute

ΔTf=1×1.86×40×1000180×200 (Mass of water=200 gas d=1 g/mL)

=2.06


Freezing point =ToΔTf
To is freezing point of water
=273.152.06

=271.09 K

=271 K

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