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Question

Which one of the following 0.10 M aqueous solutions will exhibit the largest freezing point depression ?

A
KHSO4
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B
glycine
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C
glucose
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D
hydrazine
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Solution

The correct option is A KHSO4
Freezing point depression of a solution is given by,
Tf=Kf×m
where,
Tf is the depression in freezing point.
Kf is molal depression constant.
m is molality of solution.
i is Van't hoff factor
Since, all are of 0.1 M aqueous solution,
ΔTfi

Greater the value of i, greater will be the ΔTf value.
Compound which does not show any dissociation with water will have van't hoff factor value of 1.
SoluteiGlycine1KHSO42Hydrazine1Glucose1

Hence, freezing point depression will be highest for KHSO4.

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