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Question

Outline the steps that would be necessary to convert insoluble lead II oxide into soluble lead chloride, and write the balanced equations for the reactions.


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Solution

For the required conversion, first, convert Lead oxide (PbO) to Lead nitrate (Pb(NO3)2), then Lead nitrate to lead chloride (PbCl2).

Conversion of Lead oxide to Lead nitrate

  • When Lead oxide reacts with dilute Nitric acid HNO3, it forms a soluble Lead nitrate.

The chemical reaction can be represented as:

PbO(aq)+2HNO3(dil)Pb(NO3)2(aq)+H2O(l)

Conversion of Lead nitrate to Lead chloride

  • Many salts can be prepared either by using oxide or hydroxide of the metal with the appropriate acid.
  • When Lead nitrate reacts with Sodium chloride NaCl, it forms an insoluble lead chloride along with Sodium nitrate NaNO3.

The chemical reaction can be represented as:

Pb(NO3)2(aq)+2NaCl(aq)PbCl2(s)+2NaNO3(aq)

Dissolving solid Lead chloride

  • Lead chloride is an inorganic compound that is solid at room temperature. It is insoluble in cold water.
  • However, it is soluble in hot water.
  • Thus at last, filter the precipitate of lead chloride and add water to it and boil.
  • The resulting solution will be soluble lead chloride.

In this way, insoluble lead II oxide is converted to soluble lead chloride.


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