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Question

Show that in a cubic close-packed structure, eight tetrahedral voids are present per unit cell.

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Solution

In ccp, each unit cell consists atoms at face centres and at corners.

Thus, total atoms at face centers and at corners in a unit cell =
(8×18)+(6×12)

= 1+3

= 4

So, the total number of atoms in ccp unit cell is 4.

Since tetrahedral voids are double the number of atoms in a unit cell, a ccp unit cell will contain 8 tetrahedral voids.


Let's consider a single cubic lattice consisting of 8 small cubic units. 2 tetrahedral voids are present at each body diagonal, with each void at an equal distance apart from the corner.

There are 4 body diagonals in a unit cell.
So, the total number of tetrahedral voids
= 4×2=8.



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