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Question

The conductivity of saturated solution of BaSO4 is 3.06×106 mho cm1 and its equivalent conductance is 1.53 mho cm2 eq1. The Ksp for BaSO4 will be:

A
4×1012M
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B
4×106M
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C
4×1012M2
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D
1×106M2
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Solution

The correct option is B 4×106M
Let us consider the problem:
BaSO4Ba2++SO24
ΛforNa2SO4=3.06×106Ω1
ΛeqforNa2SO4=1.53×Ω1eq1
Solubility calculated -
s=Λ×1000Λeq=3.06×106×1001.53=2×103molL1
KSP=[Na+]2[SO24]=s2
KSP=(2×103molL1)2=4×106mol3L3

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