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Question

The electronic configuration of gadolinium (Atomic number 64) is
(a) [Xe]4f35d56s2
(b) [Xe]4f75d26s1
(c) [Xe]4f75d16s2
(d) [Xe]4f85d66s2

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Solution

Answer: (c) [Xe] 4f7 5d1 6s2

The electronic configuration of La(Z=57)is[Xe]5d16s2 Therefore, further addition of electrons occurs in the lower energy 4f- orbital till it is exactly half filled at Eu (Z = 63) Thus, the electronic configuration of Eu is [Xe]4f76s2, thereafter, addition of next electron does not occur in the more stable exactly half filled 4f7 shell but occurs in the little higher energy 5d- orbital. Thus, the electronic configuration of Gd (Z=64) is [Xe] 4f7 5d1 6s2


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