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Question

The following data were obtained in experiment on inversion of cane sugar.
Time (minutes) 0 60 120 180 360
Angle of rotation +13.1 +11.6 +10.2 +9.0 +5.87 -3.8
(degree)
Determine total time ?

A
966 min
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B
483 min
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C
1932 min
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D
None of these
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Solution

The correct option is C 966 min
The integrated rate law expression for the inversion of can sugar (assuming first order kinetics) is as shown.
k=2.303tlogr0rrtr
For 60 minutes
k=2.30360log13.1(3.8)11.6(3.8)=0.001549
For 120 minutes
k=2.303120log13.1(3.8)10.2(3.8)=0.001569
For 180 minutes
k=2.303180log13.1(3.8)9.0(3.8)=0.001544
For 360 minutes
k=2.303360log13.1(3.8)5.87(3.8)=0.001551
Since, the value of k is constant, the reaction follows first order reaction.
The average value of k is 0.001549+0.001569+0.001544+0.0015514=0.00621354=0.001553min1
To determine the total time, substitute rt=0 in the above expression.
t=2.303klogr0rrtr
t=2.3030.001553log13.1(3.8)0(3.8)=966min

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