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Question

The number of atoms in the hcp unit cell is


A

4

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B

6

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C

12

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D

13

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Solution

The correct option is B

6


The explanation for the correct option

(B)6

Hexagonal close-packing

  • The second row can be stacked on top of the first in a staggered pattern such that its spheres fit in the depressions of the first row.
  • If the first row's arrangement of spheres is referred to as 'A-type, the second row's arrangement may be referred to as 'B' type.

Number of atoms in hcp unit cell

  • In HCP, there are 6 corner atoms in the top layer and 6 corner atoms in the bottom layer, so 12 atoms in the unit cell. The contribution of each atom in the unit cell is one-sixth.
  • Two atoms are present at two face centers. The contribution of each atom in the unit cell is one-half.
  • Three atoms are placed within the volume of the unit cell and the contribution of each atom is 1.
  • So, the number of atoms in the hcp unit cell is =12×16+2×12+3=6

The explanation for the incorrect option

The number of atoms in the hcp unit cell is 6. So, options (A), (C), and (D) are incorrect.

Hence, the number of atoms in the hcp unit cell is 6. Hence, option (B) is correct.


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