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Question

The number of possible optical isomers for the complexes MA2B2withsp3ordsp2 hybridized metal atom, respectively, is:


A

0and1

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B

0and0

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C

2and2

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D

0and2

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Solution

The correct option is B

0and0


The explanation for the correct option:

B: 0and0

Optical Isomers:

  • When two isomers exhibit identical molecular weight, chemical, and physical properties, this is known as optical isomerism.
  • Their impact on the rotation of polarised light, however, varies.
  • When two substances with the same molecular and structural formula cannot be superimposed on one another, optical isomerism mostly arises.

MA2B2 Complex with hybridization of sp3:

  • It will have a tetrahedral shape if Missp3 hybridized.
  • Since there will be a plane of symmetry, optical activity is not present.

MA2B2 Complex with hybridization of dsp2:

  • M will take on a square planar geometry if Misdsp2 hybridized.
  • It doesn't exhibit optical activity since there is a plane of symmetry there.

Final Answer: Therefore, Option B is the correct option.


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