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Question

The partial pressures of CH3OH,CO and H2 in the equilibrium mixture for the reaction CO+2H2CH3OH at 427oC are 2.0,1.0 and 0.1 atm respectively. The value of Kp for the decomposition of CH3OH into CO and H2 is:

A
1×102atm
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B
2×102atm1
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C
50atm2
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D
5×103atm2
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Solution

The correct option is D 5×103atm2
The decomposition reaction is :
CH3OHCO+2H2
KP=PCOP2H2PCH3OH

KP=1.0atm×(0.1atm)22.0atm

KP=5×103atm2

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