We use a solution of slaked lime to whitewash the walls. In the beginning the wall looks rough and coarse, but after 2 - 3 days the wall appears smooth and shiny. This is due to the formation of:
Calcium carbonate
Slaked lime is calcium hydroxide which reacts slowly with the carbon dioxide present in air to form thin and shiny layer of calcium carbonate. The chemical reaction is:
Ca(OH)2(aq) + CO2(g) → CaCO3(s) + H2O(l)