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Question

When 0.1 mole of NH3 is dissolved in water to make 1L of solution, the [OH] of solution is 1.34×103M.Calculate Kb for NH3

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Solution

Reaction involved-
NH3+H2ONH4++OH

Given-
4NH+4=OH=1.34×103 M
NH3 reacted =(0.11.34×103) M

Condition at equilibrium-
=(0.11.34×103) M
=0.10.00134 M
= 0.09866 M
Kb=[NH+4][OH]/[NH3]
=(1.34×103)×1.34×103)/0.09866
=1.8×105


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