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Question

When 1 gm of water changes from liquid to vapour phase at constant pressure of 1 atmosphere, the volume increases from 1cc to 1671cc. The heat of vaporisation at this pressure is 540 cal/gm. Increase in internal energy of water is
(1 atmosphere=1.01×106dyne/cm2).

A
4200 J
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B
8200 J
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C
1200 J
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D
2100 J
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Solution

The correct option is D 2100 J
Change in Internal energy = Q in - work done
It s a constant pressure work
wD=P(V2V1)
=1.01×105[1.6711]×106
=169.21s
P=1atm
=1.0.1×105Pa
=1.01×106dynecm2
Latent heat of vaporization =540calgm×(1gm)
=540cal
1cal=4.184J.
=540×4.184
=2259.36J
ΔU=2259.36169.21
=2090Joules
2100Joules

1240772_1106046_ans_38025902219d486b865baa2d5d7770b9.jpg

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