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Question

Which of the following factors is of no significance for roasting sulphide ores to the oxides and not subjecting the sulphide ores to carbon reduction directly?

A
Metal sulphides are less stable than the corresponding oxides
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B
CO2 is more volatile than CS2
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C
Metal sulphides are thermodynamically more stable than CS2
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D
CO2 is thermodynamically more stable than CS2
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Solution

The correct option is A Metal sulphides are less stable than the corresponding oxides
MS+C2M+CS2 ; ΔG1= positive

2MO+C2M+CO2 ; ΔG2= negative

This suggests that CO2 is thermodynamically more stable than CS2. Metal sulphides are thermodynamically more stable than CS2 while metal sulphides are more stable than the corresponding oxides.

So metal sulphides are less stable than the corresponding oxides

Hence option A is correct.

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