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Question

Which of the following metal halide has the highest ionic character?
(Here, M is monovalent metal)

A
MI
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B
MCl
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C
MBr
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D
MF
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Solution

The correct option is D MF
According to Fajan's rule, as the size of anion increases ionic character of the compound decreases. Since the size of F is the smallest among halides, MF has the highest ionic character.
The order of ionic character among metal halides is:
MF>MCl>MBr>MI

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