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Question

Which of the following oxidation states are the most characteristic for lead and tin respectively:

A
+2,+2
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B
+4,+2
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C
+2,+4
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D
+4,+4
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Solution

The correct option is B +2,+4
Lead and tin are in the fourth group of the periodic table,so we can expect an oxidation state of +4 for both of them.But due to the reluctance of participation of electrons in the outermost s orbital in bonding i.e., inert pair effect which increases down the group.So, the oxidation states of lead and tin are +2 and +4 respectively which is also evident from their respective chemical reactions.

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