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Question

Which of the following species is paramagnetic?

A
O2
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B
CN
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C
CO
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D
NO+
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Solution

The correct option is A O2
Using MOT, we can find magnetic behaviour of compounds.
Number of electrons in O2,CN,CO,NO+ are 17, 14, 14, 14 respectively.
O+2 =(σ1s)2<(σ1s)2<(σ2s)2<(σ2s)2<(σ2pz)2<(π2px=π2py)4<(π2px=π2py)3
O+2 is paramagnetic

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