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Question

Which of the following will react with AcOAg?

A
RNH2
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B
ROTs
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C
RN3
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D
RBr
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Solution

The correct options are
B ROTs
C RN3
D RBr
(A) Alkyl amine (RNH2) do not react with silver acetate.
(B) Alkyl tosylate reacts with silver acetate to form ester.
ROTs+CH3COOAgCH3COOR+AgOTs
(C) Alkyl azides react with silver acetate to form an ester.
CH3COOAg+RN3CH3COOR+AgN3
(D) Silver acetate reacts with Ethyl bromide to form ethyl acetate and silver bromide.
CH3COOAg+C2H5BrCH3COOC2H5+AgBr

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