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Question

Which of the pair of complex compounds are tetrahedral as well as diamagnetic?


A

[CoCl4] and [Co(CO)4]

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B

[Ag(SCN)4]2 and [NiCl4]2

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C

[Co(CO)4] and [Ni(CN)4]4

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D

[PdCl4]2 and [Ni(CN)4]2

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Solution

The correct option is C

[Co(CO)4] and [Ni(CN)4]4


Co in [Co(CO)4] :

Hybridization: sp3,
μeff=0
Ni in [Ni(CN)4]4 :

Hybridization: sp3,
μeff=0


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