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Standard XII
Chemistry
Variable Oxidation States
Why do d-bloc...
Question
Why do d-block elements form complexes?
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Solution
Transition elements form complexes readily because of the small size of the ions and higher nuclear charge, they possess high charge density.
Due to the presence of vacant d-orbitals in which a ligand can donate its electron, forms a complex.
Transition metal ions have a large polarizing power as a result they can attract lone pairs from other atoms to form complexes.
For example, elements like
Fe
+
2
and
Fe
+
3
,
Cu
+
and
Cu
+
2
shows variable oxidation state and can form a large number of complexes.
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